Hi,
If the battery voltage is much higher than the PICaxe Vdd, then you would need to put the PNP in the top of the divider chain and drive its base from the collector of an NPN (so that the PNP base/NPN collector can rise above the PICaxe's Vdd).
However, witha 4-cell (alkaline) battery you need to use at least a LOW DropOut regulator, and even that will not have any "headroom" when the batteries lose their freshness. So it's probably better to use the "normal" method mentioned above of connecting one or two forward diodes (or a LED) between the battery and PICaxe Vdd. Then you can use CALIBADC to infer the battery voltage. EDIT: It seems this paragrraph is not relevant to your clarified application.
Alternatively, (to read the voltage "accurately") if the battery voltage is only slightly above the Vdd, then you could connect the lower end of the voltage divider to a PICaxe pin and drive it low to make the measurement. When off, a small current will still flow into the ADC input pin via the (electrostatic) protection diode (to Vdd), but the current drain will be reduced by a factor of 10 or more.
EDIT: In your second diagram, the PNP will be turned on anyway, if its emitter (i.e. batttery voltage) is more than about 5.6 volts (5v + Vbe). Also, Leg 4 of an 08M2 is NOT an ADC input!
Cheers, Alan.