Always, best to post a new message rather than editing.... I can't be arsed to keep going back and forth
So, aha, an RC, the Forum crystal Ball didn't pick that up.
Well, I guess if your 7805 goes duff or you put it in the wrong way round then it could go higher.
I would think that cockups and accidents aside (oh dear) that it will be fine.
Or a fancy coupling using the controllers supply volts.
But if you are going to play around with zeners then get a selection and experiment in a breadboard. Their performance will be affected by the series resistance, which in turn will affect the pumping characteristc on your capacitor.
But if the reg is 5V then (reactance aside) it can't go higher.
If it does, then you have discovered perpetual motion, which is the feeling you get several hours after a strong curry.