Hi,
"Pin A.0" can be used in some circumstances for the Serial Output pin, but I believe there is no equivalent for the Serial Input Pin. It's also possible to do some "clever" things with READ
DAC (not ADC) on the serial output pin.
However, you can do a certain amount via the SFR registers, for example activating the Weak Pulup Resistors on those pins. They are both part of the base PIC Port A, but note that the pin numbers are different. Several other of the PICaxe B and C port pins are actually on the base PIC Port A.
Cheers, Alan.